期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 22, 页码 8137-8140出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4030269
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资金
- National Natural Science Foundation of China [21006048, 20976082]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20093221120001]
- China Postdoctoral Science Foundation [20110491406]
- Jiangsu Planned Projects for Postdoctoral Research Funds [1101155C]
- Research and Innovation Project for College Graduates of Jiangsu Province [CXZZ11_0350, CXZZ12_0432]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
Selective reduction of supported CuO to Cu2O was realized using the strategy of vapor-induced reduction, in which HCHO/H2O vapor diffuses into the pores of the support and interacts with predispersed CuO. This new strategy allows the fabrication of supported cuprous sites at much lower temperatures within a short time, avoids the formation of Cu(0) with a Cu(I) yield of nearly 100%, and results in materials with good adsorption performance, which is impossible to achieve by conventional methods.
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