期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 26, 页码 9600-9603出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja403852e
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22225004]
- GCOE Program
- Grants-in-Aid for Scientific Research [22225004] Funding Source: KAKEN
Selective hydrogenation of fluorinated esters with pincer-type bifunctional catalysts RuHCl(CO)(dpa) 1a, trans-RuH2(CO)(dpa) 1b, and trans-RuCl2(CO)(dpa) 1cunder mild conditions proceeds rapidly to give the corresponding fluorinated alcohols or hemiacetals in good to excellent yields. Under the optimized conditions, the hydrogenation of chiral (R)-2-fluoropropionate proceeds smoothly to give the corresponding chiral alcohol without any serious decrease of the ee value.
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