期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 38, 页码 14106-14109出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja408467b
关键词
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资金
- MRSEC program of the National Science Foundation [DMR 1121053]
- Dow Chemical Co. through the Dow Materials Institute at UCSB
- California NanoSystems Institute
- NSF
- UC Regents
- CSP Technologies
- DOE Office of Science (DOE-SCGF)
A modular and general method based on a photomediated ATRA reaction for the spatially controlled functionalization of surfaces with visible light is reported. The ability to control reactivity with light intensity combined with the orthogonality of ATRA chemistry allows well-defined chemically differentiated monolayers and complex nonlinear chemical concentration gradients to be easily prepared. Use of light to mediate these reactions permits spatial regulation and the generation of unique, multifunctional chemical gradients.
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