期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 21, 页码 7831-7834出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja402651q
关键词
-
资金
- NIH/NIGMS [2R01 GM 076153B]
Development of a mild (35 degrees C, no Breasted acids) tandem Wacker oxidation dehydrogenation of terminal olefins was accomplished using palladium(II) and hypervalent iodine co-catalysis. The reaction affords linear aryl and alkyl alpha,beta-unsaturated ketones directly from readily available terminal olefins in good yields (average 75% per step) with excellent functional group tolerance and chemo- and stereo-selectivities. The hypervalent iodine co-catalyst was found to be critical for dehydrogenation but was not effective as a stoichiometic oxidant.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据