期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 15, 页码 5533-5536出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja401553d
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资金
- Research Grants Council of Hong Kong [CityU 101810]
- Hong Kong University Grants Committee [AoE/P-03-08]
We report experimental and computational studies of the facile oxidative C-N bond cleavage of anilines by a (salen)rutheniurn(VI) nitrido complex. We provide evidence that the initial step involves nucleophilic attack of aniline at the nitrido ligand of the ruthenium complex, which is followed by proton and electron transfer to afford a (salen)ruthenium(II) diazonium intermediate. This intermediate then undergoes unimolecular decomposition to generate benzene and N-2.
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