期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 50, 页码 18706-18709出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja411647x
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资金
- CREST from JST
- NEXT program
- Program for Leading Graduate Schools Integrative Graduate Education and Research Program in Green Natural Sciences in Nagoya University
- Daiko Foundation
A highly diastereo- and enantioselective ring-opening alkylation of racemic 2,2-disubstituted aziridines with 3-substituted oxindoles is achieved under the catalysis of a chiral 1,2,3-triazolium salt. This reaction represents a hitherto unknown, catalytic stereoselective carbon carbon bond formation through direct substitution at the tetrasubstituted chiral carbon.
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