期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 26, 页码 9588-9591出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4031616
关键词
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资金
- National Institute of General Medical Sciences [R01 GM098340]
- UNC-CH
- Eli Lilly New Faculty Award
Herein we report a metal-free method for the direct anti-Markovnikov hydroamination of unsaturated amines. Irradiation of the amine substrates with visible light in the presence of catalytic quantities of easily synthesized 9-mesityl-10-methylacridinium tetrafluoroborate and thiophenol as a hydrogen-atom donor furnished the nitrogen-containing heterocycles with complete regiocontrol. Two examples of intermolecular anti-Markovnikov alkene hydroamination are also disclosed.
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