期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 35, 页码 12944-12947出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja4059074
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资金
- Academy of Finland
DFT computations show that calixarenes stabilize subnanometer Au-11 clusters allowing access of small molecules like O-2 to reactive metal sites in the core. Maximum of three dioxygen molecules can bind to the cluster, and they are activated to a superoxo O-2(-) state. This study predicts that gold clusters could act as viable oxidation catalysts at ambient conditions based on similar principles as the metal centers in enzymes.
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