期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 43, 页码 16066-16069出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja409330h
关键词
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资金
- NSF [CRIF-MU CHE-0840493]
- TTU Department of Chemistry & Biochemistry cluster Robinson
The synthesis, structural characterization, and acid base chemistry of [C(SiMe2OCH2CH2OMe)(3)] Na (2), a sterically encumbered zwitterionic organosodium compound, is reported. 2 is a strong Bronsted base that forms frustrated Lewis pairs (FLPs) with a number of boron-containing Lewis acids ranging from weakly Lewis acidic aryl and alkyl boranes to various alkyl borates. These intermolecular FLPs readily cleave H-2, which confirms that even poor Lewis acids can engage in FLP-mediated H-2 cleavage provided that the present bulky base is of sufficiently high Bronsted basicity.
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