4.8 Article

Magnesium-Antimony Liquid Metal Battery for Stationary Energy Storage

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 4, 页码 1895-1897

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ja209759s

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资金

  1. Deshpande Center for Technological Innovation at MIT
  2. Chesonis Family Foundation at MIT
  3. Agency-Energy (U.S. Department of Energy)
  4. Total, S.A.

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Batteries are an attractive option for grid: scale energy storage applications because of their small footprint and flexible siting. A high-temperature (700 degrees C) magnesium antimony (MgllSb) liquid metal battery comprising a negative electrode of Mg, a molten salt electrolyte (MgCL2-KCl-NaCl), and a positive electrode of Sb is proposed and characterized. Because of the immiscibility of the contiguous salt and metal phases, they stratify by density into three distinct layers. Cells were cycled at rates ranging from 50 to 200 mA/cm(2) and demonstrated up to 69% DC-DC energy efficiency. The self-segregating nature of the battery components and the use Of low-cost materials results in a promising technology for stationary energy storage applications.

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