期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 37, 页码 15173-15176出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3044954
关键词
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资金
- State Basic Research Project of China [2009CB623507]
- National Natural Science Foundation of China [21273197, U1162201]
As important industrial materials, microporous zeolites are necessarily synthesized in the presence of solvents such as in hydrothermal, solvothermal, and ionothermal routes. We demonstrate here a simple and generalized solvent-free route for synthesizing various types of zeolites by mixing, grinding, and heating solid raw materials. Compared with conventional hydrothermal route, the avoidance of solvents in the synthesis not only significantly reduces the waste production, but also greatly increases the yield of zeolite products. In addition, the use of starting solid raw materials remarkably enhances the synthesis efficiency and reduces the use of raw materials, energy, and costs.
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