期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 22, 页码 9086-9089出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja303109q
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资金
- Scientific Research from the MEXT, Japan
- Grants-in-Aid for Scientific Research [24550117] Funding Source: KAKEN
Asymmetric addition of arylboronic acids to alpha,beta-unsaturated sulfonyl compounds proceeded in the presence of a rhodium catalyst coordinated with a chiral diene ligand to give high yields of the addition products with high enantioselectivity (96 -> 99.5% ee). The diene ligand was proved to be essential for the formation of the addition products, while the use of a bisphosphine ligand mainly gave the cine-substitution product.
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