期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 42, 页码 17490-17493出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja308976x
关键词
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资金
- National Natural Science Foundation of China [NSFC-21272183, 21002077]
- Fund of New Scientific Stars of Shanxi Province [2012KJXX-26]
A Pd-catalyzed regioselective C-H bond carbonylation of N-alkyl anilines for the synthesis of isatoic anhydrides has been developed. The key Pd-catalyst intermediate has been isolated and characterized. This novel Pd-catalyzed carbonylation reaction tolerates a wide range of functional groups and is a reliable method for the rapid elaboration of readily available N-alkyl anilines into a variety of substituted isatoic anhydrides under mild conditions.
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