期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 15, 页码 6532-6535出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3007148
关键词
-
资金
- NSFC [21172207]
- MOST [2010CB833300]
- Ministry of Education
The hybrid Au(I)/Bronsted acid binary catalyst system enables enynes to serve as latent 1,3-silyloxydienes capable of participating in the first cascade hydrosiloxylation of an enynyl silanol/asymmetric Diels Alder reaction. A variety of polycyclic compounds bearing multistereogenic centers were obtained in high yields and excellent enantioselectivities from the relay catalytic cascade reaction between (2-(but-3-en-1-ynyl)phenyl) silanols and quinones catalyzed by the combined achiral gold complex and chiral N-triflyl phosphoramide.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据