期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 29, 页码 11980-11983出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja305833a
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资金
- Nanyang Technological University
- Singapore Ministry of Education [MOE2012-T2-1-014]
A method for the oxygenation of tertiary C-H bonds of N-alkylamidines and N-(2-alkylaryl)-amidines is described that utilizes the CuBr center dot SMe2/2,2'-bipyridine catalytic system under an O-2 atmosphere and provides dihydrooxazoles, and 4H-1,3-benzoxazines. The oxygen atom is incorporated from atmospheric molecular oxygen during the present process.
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