期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 22, 页码 9046-9049出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja302071t
关键词
-
资金
- U.S. DOE Office of Nuclear Energy
Krypton (Kr) and xenon (Xe) adsorption on two partially fluorinated metal organic frameworks (FMOFCu and FMOFZn) with different cavity size and topologies are reported. FMOFCu shows an inversion in sorption selectivity toward Kr at temperatures below 0 degrees C while FMOFZn does not. The 1D microtubes packed along the (101) direction connected through small bottleneck windows in FMOFCu appear to be the reason for this peculiar behavior. The FMOFCu shows an estimated Kr/Xe selectivity of 36 at 0.1 bar and 203 K.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据