A Physical Approach To Specifically Improve the Mobility of Alkane Liquid Drops

Seamless control of resistance to liquid drop movement for polar (water) and nonpolar alkane (n-hexadecane, n-dodecane, and n-decane) probe liquids on substrate surfaces was successfully demonstrated using molten linear poly(dimethylsiloxane) (PDMS) brush films with a range of different molecular weights (MWs). The ease of movement of liquid drops critically depended on polymer chain mobility as it relates to both polymer MW and solvent swelling on these chemically- and topographically identical surfaces. Our brush films therefore displayed lower resistances to liquid drop movement with decreasing polymer MW and surface tension of probe liquid as measured by contact angle (CA) hysteresis and tilt angle measurements. Subsequently, while mobility of water drops was inferior and became worse at higher MWs, n-decane drops were found to experience little resistance to movement on these polymer brush films. Calculating CA hysteresis as Delta theta(cos) = cos theta(R) - cos theta(A) (theta(A) and theta(R) are the advancing and receding CAs, respectively) rather than the standard Delta theta = theta(A) - theta(R) was found to be advantageous for estimation of the actual dynamic dewetting behavior of various probe liquids on an inclined substrate.