期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 21, 页码 8786-8789出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja302807s
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资金
- Center for Process Analytical Chemistry at the University of Washington
- Chemical Science, Geosciences and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy [DE-FG02-07ER15913]
We report crystalline mixed-ligand copper complexes with phenanthroline and isocyanides with almost rnillesecond emission lifetimes that are efficient dioxygen sensors. The oxygen sensitivity of the prototype ([Cu(CN-xylyl)(2)(dmp)]tfpb, dmp = 2,9-dimethy1-1,10-phenanthroline; CN-xylyl = 2,6-dimethylphenylisocyanide; tfpb = tetralcis(bis-3,5-trifluoromethylphenylborate) is 38 times better than that of [Ru(phen)(3)]tfpb(2) (phen = 1,10-phenanthroline).
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