期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 7, 页码 3342-3345出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja211837f
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资金
- Air Force Office of Scientific Research (AFOSR) [FA9950-09-1-0193, FA9550-09-1-0254]
Two enantiomeric light-driven azo molecular switches with axial chirality and extended conjugation were found to exhibit unprecedented reversible photo-isomerization in both organic-solvent and liquid-crystal media only upon visible-light irradiation. When doped in an achiral liquid crystal with a different concentration, the chiral switch was able either to immediately induce an optically tunable helical superstructure or to retain an achiral liquid-crystal phase whose helical superstructure was induced and tuned reversibly upon visible-light irradiation. Furthermore, reversible dynamic red, green, and blue reflection achieved only by using visible light was demonstrated.
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