期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 14, 页码 6104-6107出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja301134e
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资金
- Agence Nationale de la Recherche (ANR) [2010 BLAN 0808]
Electrochemical investigation of a boron-capped tris(glyoximato)cobalt clathrochelate complex in the presence of acid reveals that the catalytic activity toward hydrogen evolution results from an electro-deposition of cobalt-containing nanoparticles on the electrode surface at a modest cathodic potential. The deposited particles act as remarkably active catalysts for H-2 production in water at pH 7.
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