期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 17, 页码 7325-7328出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja302710v
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资金
- National Science of Foundation [CHE-1011891]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1011891] Funding Source: National Science Foundation
A well-defined cationic Ru-H complex catalyzes the dehydrative C-H alkylation reaction of phenols with alcohols to form ortho-substituted phenol products. Benzofuran derivatives are efficiently synthesized from the dehydrative C-H alkenylation and annulation reaction of phenols with 1,2-diols. The catalytic C-H coupling method employs cheaply available phenols and alcohols, exhibits a broad substrate scope, tolerates carbonyl and amine functional groups, and liberates water as the only byproduct.
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