4.8 Article

Redox-Neutral α-Cyanation of Amines

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 37, 页码 15305-15308

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AMER CHEMICAL SOC
DOI: 10.1021/ja308009g

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资金

  1. National Science Foundation [CHE-0911192]
  2. Amgen Young Investigator Award
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [0911192] Funding Source: National Science Foundation

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alpha-Aminonitriles inaccessible by traditional Strecker chemistry are obtained in redox-neutral fashion by direct amine alpha-cyanation/N-alkylation or alternatively, alpha-aminonitrile isomerization. These unprecedented transformations are catalyzed by simple carboxylic acids.

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