期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 13, 页码 5798-5800出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja211601k
关键词
-
资金
- National Institutes of Health [CA-115531, CA-126608, RR-02584, EB-00482]
- Robert A. Welch Foundation [AT-584]
PARACEST redox sensors containing the NAD(+)/NADH mimic N-methylquinolinium moiety as a redox-active functional group have been designed and synthesized. The Eu3+ complex with two quinolinium moieties was nearly completely CEST-silent in the oxidized form but was turned on upon reduction with beta-NADH. The CEST effect of the Eu3+ complex containing only one quinolinium group was much less redox-responsive but showed an unexpected sensitivity to pH in the physiologically relevant pH range.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据