期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 46, 页码 18886-18888出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja307713q
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资金
- University of Pittsburgh
- University of Pittsburgh Dietrich School of Arts and Sciences
Strain-promoted click chemistry is used to post synthetically modify the pore walls of azide-functionalized mesoporous bio-MOE-100 (N-3-bio-MOE-100). The reactions proceed in high yield and produce no byproduct. This new method was used to introduce various functional groups into the MOF mesopores, including succinimidyl ester bioconjugation moieties that allow for straightforward coupling of biomolecules to the pore walls.
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