期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 4, 页码 2148-2153出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja208706c
关键词
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资金
- MEXT [22000008]
- Grants-in-Aid for Scientific Research [22000008] Funding Source: KAKEN
Here we show that essentially any Fe compounds spanning Fe salts, nanoparticles, and buckyferrocene could serve as catalysts for single-walled carbon nanotube (SWNT) forest growth when supported on AlOx and annealed in hydrogen. This observation was explained by subsurface diffusion of Fe atoms into the AlOx support induced by hydrogen annealing where most of the deposited Fe left the surface and the remaining Fe atoms reconfigured into small nanoparticles suitable for SWNT growth. Inerestingly, the average diameters of the SWNTs grown from all iron compounds studied were nearly identical (2.8-3.1 nm). We interpret that the offsetting effects of Ostwald ripening and subsurface diffusion resulted in the ability to grow SWNT forests with similar average diameters regardless of the initial Fe catalyst.
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