期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 13, 页码 5766-5769出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja301153k
关键词
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资金
- National Natural Science Foundation of China [21025206, 20832003, 20972118]
- MOST of China [2011CB808600]
- Fundamental Research Funds for the Central Universities
- Program for New Century Excellent Talents in University (NCET)
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
A novel silver-mediated highly selective oxidative C-H/C-H functionalization of 1,3-dicarbonyl compounds with terminal alkynes for the creation of polysubstituted furans and pyrroles in one step has been demonstrated. Promoted by the crucial silver species, perfect selectivity and good to excellent yields could be achieved. This protocol represents an extremely simple and atom-economic way to construct polysubstituted furans and pyrroles from basic starting materials under mild conditions.
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