期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 3, 页码 1438-1441出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja209688a
关键词
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资金
- Spanish MICINN [MAT2008-05779, MAT2008-03400-E/MAT, CDS2009-00050, CSD2009-00013, ENE2008-03277-E/CON]
- Ramon y Cajal Program
A procedure for the continuous production of Cu2ZnSnS4 (CZTS) nanoparticles with controlled composition is presented. CZTS nanoparticles were prepared through the reaction of the metals' amino complexes with elemental sulfur in a continuous-flow reactor at moderate temperatures (300-330 degrees C). High-resolution transmission electron microscopy and X-ray diffraction analysis showed the nanocrystals to have a crystallographic structure compatible with that of the kesterite. Chemical characterization of the materials showed the presence of the four elements in each individual nanocrystal. Composition control was achieved by adjusting the solution flow rate through the reactor and the proper choice of the nominal precursor concentration within the flowing solution. Single-particle analysis revealed a composition distribution within each sample, which was optimized at the highest synthesis temperatures used.
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