4.8 Article

Continuous-Flow Synthesis of Monoarylated Acetaldehydes Using Aryldiazonium Salts

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 30, 页码 12466-12469

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AMER CHEMICAL SOC
DOI: 10.1021/ja305660a

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资金

  1. Novartis International AG
  2. National Science Foundation [CHE-9808061, DBI-9729592]
  3. National Institutes of Health [1S10RR13886-01]

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Anilines and ethyl vinyl ether can be used as precursors for a process that is the synthetic equivalent of the alpha-arylation of acetaldehyde enolate. The reaction manifests a high level of functional group compatibility, allowing the ready preparation of a number of synthetically valuable compounds.

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