4.8 Article

Iron Sulfide Catalyzed Redox/Condensation Cascade Reaction between 2-Amino/Hydroxy Nitrobenzenes and Activated Methyl Groups: A Straightforward Atom Economical Approach to 2-Hetaryl-benzimidazoles and -benzoxazoles

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 1, 页码 118-121

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AMER CHEMICAL SOC
DOI: 10.1021/ja311780a

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  1. CNRS
  2. ICSN

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Iron sulfide generated in situ from elemental sulfur and iron was found to be highly efficient in catalyzing a redox/condensation cascade reaction between 2-amino/hydroxy nitrobenzenes and activated methyl groups. This method represents a straightforward and highly atom economical approach to 2-hetaryl-benzimidazoles and -benzoxazoles.

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