期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 24, 页码 9840-9843出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja301044p
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资金
- Deutsche Forschungsgemeinschaft (DFG) [PO 1602/1-1]
- Swiss National Science Foundation (SNF) [200021 129861]
- Swiss National Science Foundation (SNF) [200021_129861] Funding Source: Swiss National Science Foundation (SNF)
The magnetism of DySc2N@C-80 endofullerene was studied with X-ray magnetic circular dichroism (XMCD) and a magnetometer with a superconducting quantum interference device (SQUID) down to temperatures of 2 K and in fields up to 7 T. XMCD shows hysteresis of the 4f spin and orbital moment in Dy-III ions. SQUID magnetometry indicates hysteresis below 6 K, while thermal and nonthermal relaxation is observed. Dilution of DySc2N@C-80 samples with C-60 increases the zero-field 4f electron relaxation time at 2 K to several hours.
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