期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 29, 页码 11932-11935出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja304818c
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [23655056]
- Grants-in-Aid for Scientific Research [23655056, 23750063] Funding Source: KAKEN
The first catalytic double hydrophosphination of alkynes was achieved by reaction with diarylphosphines in the presence of an iron catalyst. The double hydrophosphination proceeded regioselectively and effectively for various secondary arylphosphines and terminal alkynes to give 1,2-bisphosphinoethane derivatives.
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