期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 5, 页码 2504-2507出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja211092q
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The zinc(II)-catalyzed redox cross-dehydrogenative coupling (CDC) of propargylic amines and terminal alkynes proceeds to afford N-tethered 1,6-enynes. In the current CDC reaction, a C(sp)-C(sp(3)) bond is formed between the carbon adjacent to the nitrogen atom in the propargylic amine and the terminal carbon of the alkyne with reduction of the C-C triple bond of the propargylic amine, which acts as an internal oxidant.
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