期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 5, 页码 2547-2550出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja212020b
关键词
-
资金
- NIH/NIGMS [GM-097444]
- Swiss National Science Foundation
Intermolecular Ritter-type C-H amination of unactivated sp(3) carbons has been developed. This new reaction proceeds under mild conditions using readily available reagents and an inexpensive source of nitrogen (acetonitrile). A broad scope of substrates can be aminated with this method since many functional groups are tolerated. This reaction also allows for the direct, innate C H amination of a variety of hydrocarbons such as cyclohexane without the need of prefunctionalization or installation of a directing group.
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