期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 25, 页码 10325-10328出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja303121v
关键词
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资金
- European Research Council [ERC 246837]
- Minerva Foundation
- Kimmel Center for Molecular Design
Primary alcohol dehydrogenation by a PNP-Ru(II) catalyst was probed by low-temperature NMR experiments. Facile dehydrogenation occurred at -30 degrees C, but the resulting aldehydes were not found in solution, as they were trapped by the catalyst through a new mode of metal-ligand cooperation involving Ru-O coordination and an unusual, highly reversible C-C coupling with the PNP pincer ligand.
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