期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 25, 页码 10397-10400出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja304609n
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资金
- NSF [CHE0909587]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0909587] Funding Source: National Science Foundation
- Engineering and Physical Sciences Research Council [EP/J003921/1] Funding Source: researchfish
- EPSRC [EP/J003921/1] Funding Source: UKRI
Addition of the Lewis acid Zn2+ to (TBP(8)Cz)Mn-V(O) induces valence tautomerization, resulting in the formation of [(TBP(8)Cz(+center dot))Mn-IV(O)-Zn2+]. This new species was characterized by UV-vis, EPR, the Evans method, and H-1 NMR and supported by DFT calculations. Removal of Zn2+ quantitatively restores the starting material. Electron-transfer and hydrogen-atom-transfer reactions are strongly influenced by the presence of Zn2+.
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