期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 5, 页码 2551-2554出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja2119892
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资金
- BP
- EPSRC
- NSERC
- University of Huelva
Photolytic ligand displacement and salt metathesis routes have been exploited to give access to kappa(1) sigma-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related kappa(2) complex of [Cr(CO)(4)]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as sigma-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes.
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