4.8 Article

3D Continuous Water Nanosheet as a Gyroid Minimal Surface Formed by Bicontinuous Cubic Liquid-Crystalline Zwitterions

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 28, 页码 11354-11357

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AMER CHEMICAL SOC
DOI: 10.1021/ja304124w

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资金

  1. Japan Society for the Promotion of Science [21225007]
  2. [23750147]
  3. Grants-in-Aid for Scientific Research [23750147, 21225007] Funding Source: KAKEN

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Co-organization of amphiphilic zwitterions and bis(trifluoromethanesulfonyl)imide led to the formation of bicontinuous cubic liquid-crystalline structures having 3D continuous hydrophilic gyroid minimal surface. The gyroid surface, incorporating a small amount of water, provided extremely thin but macroscopically continuous water nanosheet with a thickness of approximately 5 angstrom. The water nanosheet functioned as alignment free proton conduction pathway.

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