期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 45, 页码 18566-18569出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja309311z
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资金
- NIH [2R01GM068433]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048528] Funding Source: National Science Foundation
The first example of a Cu-catalyzed asymmetric O-nitrosocarbonyl aldol reaction is described. This novel protocol allows convenient access to highly enantioenriched alpha-hydroxy-beta-ketoesters including the antibacterial natural. product kjellmanianone (up to 99% ee). MnO2 was introduced. as a:mild efficient oxidant for the in situ generation of nitrosocarbonyl species from hydroxamic acid derivatives.
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