期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 36, 页码 14760-14763出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja307771d
关键词
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资金
- Grant-in-Aid for the Global COE Program Integrated Materials Science from the Ministry of Education, Culture, Sports, Science and Technology of Japan
- JSPS
Aryl triflates were transformed to aryl bromides/iodides simply by treating them with LiBr/NaI and [Cp*Ru(MeCN)(3)]OTf. The ruthenium complex also catalyzed the transformation of alkenyl sulfonates and phosphates to alkenyl halides under mild conditions. Aryl and alkenyl triflates undergo oxidative addition to a ruthenium(II) complex to form eta(1)-arylruthenium and 1-ruthenacyclopropene intermediates, respectively, which are transformed to the corresponding halides.
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