期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 47, 页码 19366-19369出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja309963w
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资金
- Commons from JST
- Grants-in-Aid for Scientific Research [11J07922] Funding Source: KAKEN
The first highly enantioselective desymmetrization of aziridines with phosphites has been developed. Excellent yields and enantio-selectivities were observed for the reaction with various aziridines using a new class of readily accessible chiral catalysts derived from 9-amino-9-deoxy-epi-cinchonas alkaloids. In studies probing the reaction mechanism, we observed some complexes for the cinchona alkaloid amide-Zn(II) by ESI-MS analysis
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