期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 30, 页码 12454-12457出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja305801m
关键词
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资金
- National Natural Science Foundation of China [21072018, 20632008]
- National Basic Research Program of China [2012CB21600]
A metal-free oxidative trifluoromethyl-thiolation of terminal alkynes using readily available CF3SiMe3 and elemental sulfur at room temperature has been developed. This reaction provides an efficient and convenient method for the preparation of alkynyl trifluoromethyl sulfides bearing a wide range of functional groups. Preliminary investigation revealed that elemental sulfur instead of air acted as the oxidant.
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