期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 42, 页码 17470-17473出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja308613b
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资金
- National Science and Engineering Council of Canada (NSERC)
- Ontario Research and Development Challenge Fund (ORDCF)
- Ontario Graduate Scholarship Program (OGS)
- Ontario Centre of Excellence (OCE)
The cross-coupling reactions of allylboronic acid pinacol ester derivatives with aryl and heteroaryl halides occurred with high selectivity (> 97%) at the acarbon of the allylboron reagent in the presence of Pd-PEPPSI-IPent precatalyst and 5 M KOH in refluxing THF. In the case of trisubstituted allylboronates with different substituents on the olefin, minor olefin geometry isomerization was observed (E/Z approximate to 80/20).
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