期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 49, 页码 20146-20150出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3091033
关键词
-
资金
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan
- JSPS KAKENHI [23655210]
- Grants-in-Aid for Scientific Research [23655210] Funding Source: KAKEN
A new water-soluble thermoresponsive pillar[6]arene with triethylene oxide groups was synthesized. The pillar[6]arene showed lower critical solution temperature behavior in aqueous solution. Its clouding point was photoreversibly switched based on a photoresponsive host-guest system. The trans form of an azobenzene guest formed a stable 1:1 complex with the pillar[6]arene. Complexation increased the clouding point. Irradiation with UV light induced a conformation change for the azobenzene guest from the trans to cis form, and dethreading occurred because of a size mismatch between the cis form and the pillar[6]arene cavity. This dethreading decreased the clouding point. The photoresponsive host-guest system was reversible, and the clouding point could be switched by alternating irradiation with UV or visible light. We demonstrated photoresponsive reversible clear-to-turbid and turbid-to-clear transitions for the solution based on the reversible switching of the clouding point using the photosensitive host-guest system.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据