期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 38, 页码 15664-15667出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja306992k
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资金
- Japan Society for the Promotion of Science (JSPS)
- Nagoya University Global COE program for fellowships
- National Science Foundation
- Department of Energy
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1149096] Funding Source: National Science Foundation
All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.
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