期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 2, 页码 644-647出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja312150d
关键词
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资金
- Chemiderm, Inc.
- NSF
A modular, 18-step total synthesis of hyperforin is described. The natural product was quickly accessed using latent symmetry elements, whereby a group-selective, Lewis acid-catalyzed epoxide-opening cascade cyclization was used to furnish the bicyclo[3.3.1]-nonane core and set two key quaternary stereocenters.
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