期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 31, 页码 12943-12946出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3068269
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资金
- Austrian Science Fund (FWF) [J 3053-N19]
Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels-Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and gamma'-addition products, respectively. The nature of the transformations and the intermediates involved are investigated by computational calculations and NMR analysis.
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