4.8 Article

Nitrogen-Doped Colloidal Graphene Quantum Dots and Their Size-Dependent Electrocatalytic Activity for the Oxygen Reduction Reaction

期刊

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 46, 页码 18932-18935

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ja309270h

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资金

  1. NSF [DMR-1105185, CMMI-1000768]
  2. AFOSR [FA9550-12-1-0037, FA2386-10-1-4071]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Materials Research [1105185] Funding Source: National Science Foundation
  5. Directorate For Engineering
  6. Div Of Civil, Mechanical, & Manufact Inn [1000768] Funding Source: National Science Foundation

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Nitrogen doping has been a powerful way to modify the properties of carbon materials ranging from activated carbon to graphene. Here we report on a solution chemistry approach to nitrogen-doped colloidal graphene quantum dots with well-defined structures. N-doping was demonstrated to significantly affect the properties of the quantum dots, including the emergence of size-dependent electrocatalytic activity for the oxygen reduction reaction.

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