期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 17, 页码 7207-7210出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja300064t
关键词
-
资金
- 973 Program of China [2012CB933802, 2009CB939701]
- NSFC [21174051, 20974038, 20921003, 50973039, 91123031]
- MOST of China
Enhancement of Se solubility in organic solvents without the use of alkylphosphine ligands is the key for phosphine-free synthesis of selenide semiconductor nanocrystals (NCs). In this communication, we demonstrate the dissolution of elemental Se in oleylamine by alkylthiol reduction at room temperature, which generates soluble alkylammonium selenide. This Se precursor is highly reactive for hot-injection synthesis of selenide semiconductor NCs, such as Cu2ZnSnSe4, Cu(InGa)Se-2, and CdSe. In the case of Cu2ZnSnSe4, for example, the as-synthesized NCs possessed small size, high size monodispersity, strong absorbance in the visible region, and in particular a promising increase in photocurrent under AM1.5 illumination. The current preparation of the Se, precursor is simple and convenient, which will promote the synthesis and practical applications of selenide NCs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据