期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 25, 页码 10329-10332出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja3032345
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A highly stereoselective catalytic alkylation sequence for the synthesis of highly functionalized and versatile five-membered-ring compounds bearing all-carbon quaternary stereocenters was developed. Enantioselective desymmetrization of achiral cyclopentene-1,3-diones was thus executed by chiral Cu-phosphoramidite catalysts. A variety of complicated cyclopentane derivatives can be synthesized with excellent stereoselectivities using a low catalyst loading in a one-pot operation.
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