期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 134, 期 3, 页码 1471-1473出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja210976a
关键词
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资金
- Swiss National Science Foundation
- EPFL
Chemically induced bond cleavage of nitrous oxide typically proceeds by rupture of he N-O bond with concomitant O-atom transfer and liberation of dinitrogen. On a few occasions, N-N bond scission has been observed instead. We report a reaction sequence involving an N-heterocyclic carbene and a vanadium complex that results in cleavage of both the N-O bond and the N-N bond.
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